Usando o exemplo retorna esse erro:
Inicio TNFeEnvEvento
ERRO:
Erro Interno: 0
Erro HTTP: 404
URL: https://nfe.svrs.rs.gov.br/ws/recepcaoevento/recepcaoevento.asmx
<!DOCTYPE html>
<html>
<head>
<title>The resource cannot be found.</title>
<meta name="viewport" content="width=device-width" />
<style>
body {font-family:"Verdana";font-weight:normal;font-size: .7em;color:black;}
p {font-family:"Verdana";font-weight:normal;color:black;margin-top: -5px}
b {font-family:"Verdana";font-weight:bold;color:black;margin-top: -5px}
H1 { font-family:"Verdana";font-weight:normal;font-size:18pt;color:red }
H2 { font-family:"Verdana";font-weight:normal;font-size:14pt;color:maroon }
pre {font-family:"Consolas","Lucida Console",Monospace;font-size:11pt;margin:0;padding:0.5em;line-height:14pt}
.marker {font-weight: bold; color: black;text-decoration: none;}
.version {color: gray;}
.error {margin-bottom: 10px;}
.expandable { text-decoration:underline; font-weight:bold; color:navy; cursor:pointer; }
@media screen and (max-width: 639px) {
pre { width: 440px; overflow: auto; white-space: pre-wrap; word-wrap: break-word; }
}
@media screen and (max-width: 479px) {
pre { width: 280px; }
}
</style>
</head>
<body bgcolor="white">
<span><H1>Server Error in '/WS/RecepcaoEvento' Application.<hr width=100% size=1 color=silver></H1>
<h2> <i>The resource cannot be found.</i> </h2></span>
<font face="Arial, Helvetica, Geneva, SunSans-Regular, sans-serif ">
<b> Description: </b>HTTP 404. The resource you are looking for (or one of its dependencies) could have been removed, had its name changed, or is temporarily unavailable. Please review the following URL and make sure that it is spelled correctly.
<br><br>
<b> Requested URL: </b>/ws/recepcaoevento/recepcaoevento.asmx<br><br>
</font>
</body>
</html>